Split Topic.
@clivesgarage your error is different.
I would remove the PPA's for mc3man and ffmulticonverter
Uncheck the PPA from "Software and Updates" under the "Other Software" tab..
There are ways to add the key, but not certain you want to - Precise is Ubuntu 12.04 where as LL 5.x is based on Focal 20.04.
See 'Software and Updates' likely under other software.
Once removed, then run updates.